IRON (II) IODIDE

Base Information

• Chemical Name: IRON (II) IODIDE
• CAS No.: 7783-86-0
• Molecular Formula: FeI₂
• Molecular Weight: 309.656
• Hs Code.: 2827600000
• Wikipedia: Iron(II) iodide,Iron(II)_iodide
• Wikidata: Q3786756
• Mol file: 7783-86-0.mol

Synonyms:Ferrousiodide;Iron diiodide;Iron protoiodide;Iron(II) iodide;Iron iodide (FeI2);

Chemical Property of IRON (II) IODIDE

Chemical Property:

• Appearance/Colour: black crystalline powder
• Melting Point: 587 °C
• Boiling Point: 1093 °C at 760 mmHg
• PSA: 0.00000
• Density: 5.32 g/mL at 25 °C
• LogP: 1.76890
• Sensitive.: Hygroscopic
• Solubility.: H2O: soluble(lit.)
• Water Solubility.: Soluble in water, diethyl ether and ethanol.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 309.74388
• Heavy Atom Count: 3
• Complexity: 2.8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Iron(II) iodide anhydrous, beads, 10 mesh, ≥99.99% trace metals basis ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 61-20/21/22-36/37/38
• Safety Statements: 53-22-26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Fe](I)I
• Uses: Iron(II) iodide is used as a catalyst in organic reactions. As catalyst for organic reactions.

Technology Process of IRON (II) IODIDE

There total 32 articles about IRON (II) IODIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 26.0%

π-allyltricarbonyliron iodide → iron pentacarbonyl (13463-40-6,37220-42-1) + propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) + 1,4-Pentadiene (591-93-5) + ferrous iodide (7783-86-0)

Guidance literature:

In ethanol; in boiling alcohol: with further six unidentified products;

Reference yield: 0.2%

methanol (67-56-1) + iron + tert-Butyl iodide (558-17-8) → Fe(2+)*2I(1-)*2CH4O + ferrous iodide (7783-86-0)

Guidance literature:

at 20 ℃; for 168h; Inert atmosphere;

DOI:10.1039/d1dt02523f

Reference yield:

π-allyltricarbonyliron iodide → iron pentacarbonyl (13463-40-6,37220-42-1) + 1,4-Pentadiene (591-93-5) + ferrous iodide (7783-86-0)

Guidance literature:

In toluene; in air stream at 100-110°C;

upstream raw materials:

iodine

iron

sulfur dioxide

iron pentacarbonyl

Downstream raw materials:

bis{bis(diphenylphosphino)methane}di-iodoiron

tetraethylammonium tetraiodoferrate(III)

tetraethylammonium tetraiodoferrate(III)

C₃₇H₅₅FeI₂P₃

Refernces

• 1、 Gritzner, G.,Linert, W.,Gutmann, V.. "-". . p. 1193 - 1200. Retrieved 1981.
• 2、 Mucklejohn, S. A.,O'Brien, N. W.,Brumleve, T. R.. "High-Purity Iron(II) Iodide: Preparation, Vapor Pressure, and Vapor Composition, 792 to 1138 K". . p. 2409 - 2415. Retrieved 1985.
• 3、 Creutz, Sidney E.,Peters, Jonas C.. "Catalytic reduction of N2 to NH3 by an Fe-N 2 complex featuring a C-atom anchor". . p. 1105 - 1115. Retrieved 2014/02/14.