alpha-Cedrene epoxide

Base Information

• Chemical Name: alpha-Cedrene epoxide
• CAS No.: 29597-36-2
• Deprecated CAS: 11000-57-0,21996-68-9,1789709-51-8
• Molecular Formula: C15H24 O
• Molecular Weight: 220.355
• Hs Code.: 2932999099
• European Community (EC) Number: 249-717-2,236-971-4
• NSC Number: 371728
• DSSTox Substance ID: DTXSID30860119
• Nikkaji Number: J286.908J
• Wikidata: Q67879665
• Mol file: 29597-36-2.mol

Synonyms:alpha-Cedrene epoxide;8,9-Epoxycedrane;Cedrene epoxide;Andrane;Cedr-8-ene epoxide;8,9-Epoxy-cedrane;Cedrane, 8,9-epoxide;Cedrane, 8,9alpha-epoxy-;29597-36-2;NSC 371728;13567-39-0;EINECS 236-971-4;EINECS 249-717-2;AI3-36592;2,6,6,8-tetramethyl-9-oxatetracyclo[5.4.1.01,5.08,10]dodecane;2H-2a,7-Methanoazuleno[5,6-b]oxirene, octahydro-3,6,6,7a-tetramethyl-;2H-2a,7-Methanoazuleno(5,6-b)oxirene, octahydro-3,6,6,7a-tetramethyl-;(1aS-(1aalpha,2abeta,3aalpha,5aalpha,7beta,7aalpha))-Octahydro-3,6,6,7a-tetramethyl-2H-2a,7-methanoazuleno(5,6-b)oxirane;2H-2a,7-Methanoazuleno(5,6-b)oxirene, octahydro-3,6,6,7a-tetramethyl-, (1aS,2aR,3R,5aS,7R,7aR)-;Di-epi-cedrenoxide;Octahydro-3,6,6,7a-tetramethyl-2H-2a,7-methanoazuleno(5,6-b)oxirene;(1AS-(1aalpha,2abeta,3alpha,5aalpha,7beta,7aalpha))-octahydro-3,6,6,7a-tetramethyl-2H-2a,7-methanoazuleno(5,6-b)oxirene;2H-2a,7-Methanoazuleno[5,6-b]oxirene, octahydro-3,6,6,7a-tetramethyl-, (1aS,2aR,3R,5aS,7R,7aR)-;.alpha.-Cedrene epoxide;Diepi-.alpha.-cedrene epoxide;Cedrane, 8,9.alpha.-epoxy-;Cedrene oxide;Octahydro-3,6,6,7a-tetramethyl-2H-2a,7-methanoazuleno[5,6-b]oxirene;[1aS-(1aalpha,2abeta,3alpha,5aalpha,7beta,7aalpha)]-octahydro-3,6,6,7a-tetramethyl-2H-2a,7-methanoazuleno[5,6-b]oxirene;.alpha.-Cedrene oxide;.alpha.-Cedren epoxide;SCHEMBL1640421;8.xi.-Cedrane, 8,9-epoxy-;DTXSID30860119;CHEBI:167349;(1aS - (1aa,2ab,3a,5aa,7b,7aa)) - octahydro - 3,6,6,7a - tetramethyl - 2H - 2a,7 - methanoazuleno(5,6 - b) oxirene;2H-2a,7-Methanoazuleno[5,6-b]oxirene, octahydro-3,6,6,7a-tetramethyl-, [1aS-(1a.alpha.,2a.beta.,3.alpha.,5a.alpha.,7.beta.,7a.alpha.)]-;NSC371728;AKOS015901736;NSC-371728;CC1CCC2C(C)(C)C3CC12CC4OC34C;LS-52676;Q67879665;1a,3,4,5,5a,6,7,7a-Octahydro-3,6,6,7a-tetramethyl-2H-2a,7-methanoazuleno[5,6-b]oxirene

Chemical Property of alpha-Cedrene epoxide

Chemical Property:

• Boiling Point: 264.4 °C at 760 mmHg
• Flash Point: 96.6 °C
• PSA: 12.53000
• Density: 1.04 g/cm³
• LogP: 3.62780
• XLogP3: 3.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 220.182715385
• Heavy Atom Count: 16
• Complexity: 360

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC1CCC2C13CC(C2(C)C)C4(C(C3)O4)C

Technology Process of alpha-Cedrene epoxide

There total 4 articles about alpha-Cedrene epoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

(+/-)-α-Cedrene (19069-48-8) → octahydro-3,6,6,7a-tetramethyl-2H-2a,7-methanoazuleno[5,6-b]oxirene (29597-36-2)

Guidance literature:

With sodium perborate; acetic anhydride; In dichloromethane; Ambient temperature; 16-24 h;

DOI:10.1016/0040-4039(88)85059-7

Reference yield:

→ 8α:9-Epoxy-cedron (13567-39-0,29597-36-2,141662-60-4,143393-88-8)

Guidance literature:

α-Cedren, t-Amylhydroperoxid, Mo(CN)6, Bz./Δ;

Reference yield:

→ C15H24O (13567-39-0,29597-36-2,141662-60-4,143393-88-8)

Guidance literature:

2, p-Nitroperbenzoesaeure;

DOI:10.1016/S0040-4020(01)93408-8

upstream raw materials:

(+/-)-α-Cedrene

Downstream raw materials:

3,6,8,8-tetramethyl-hexahydro-3a,7-methano-azulen-5-one

Refernces