Ethylsulfanylethane; platinum(2+); dichloride

Base Information

• Chemical Name: Ethylsulfanylethane; platinum(2+); dichloride
• CAS No.: 15442-57-6
• Molecular Formula: C₈H₂₀Cl₂PtS₂
• Molecular Weight: 446.365
• DSSTox Substance ID: DTXSID50933470
• Mol file: 15442-57-6.mol

Synonyms:ethylsulfanylethane;platinum(2+);dichloride;DTXSID50933470;AKOS015901903;A809530;Platinum(2+) chloride--(ethylsulfanyl)ethane (1/2/2);cis-Dichlorobis(diethylsulfide)platinum(II)

Chemical Property of Ethylsulfanylethane; platinum(2+); dichloride

Chemical Property:

• Appearance/Colour: Yellow-green powder
• Melting Point: 105 °C(lit.)
• Boiling Point: 94.4 °C at 760 mmHg
• PSA: 50.60000
• LogP: 4.89530
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Solubility.: Soluble in acetone, alcohol and benzene
• Water Solubility.: slightly soluble
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 445.003143
• Heavy Atom Count: 13
• Complexity: 11.1

Purity/Quality:

98%,99%, ^*data from raw suppliers

cis-Dichlorobis(diethylsulfide)platinum(II), 99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCSCC.CCSCC.[Cl-].[Cl-].[Pt+2]

Technology Process of Ethylsulfanylethane; platinum(2+); dichloride

There total 27 articles about Ethylsulfanylethane; platinum(2+); dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

potassium tetrachloroplatinate(II) (10025-99-7) + diethyl sulphide (352-93-2) → cis-dichlorobis(diethylsulfide)platinum(II) (14873-92-8,20244-83-1,15337-84-5,15442-57-6) + trans-dichlorobis(diethyl sulfide)platinum(II) (14873-92-8,20244-83-1,15442-57-6,15337-84-5)

Guidance literature:

In water; byproducts: KCl; (inert atm.); addn. of diethylsulfide to aq. soln. of platinum compd., stirring for 24 h; evapn. at 25°C in vac., extn. (hot benzene), filtration, concg., cooling to 0°C, filtration, washing with hexane, NMR;

DOI:10.1021/om700997v

Reference yield: 83.0%

potassium tetrachloroplatinate(II) (10025-99-7) + diethyl sulphide (352-93-2) → cis-dichlorobis(diethylsulfide)platinum(II) (14873-92-8,20244-83-1,15337-84-5,15442-57-6) + trans-dichlorobis(diethyl sulfide)platinum(II) (14873-92-8,20244-83-1,15442-57-6,15337-84-5)

Guidance literature:

In water; byproducts: KCl; (inert atm.); addn. of diethylsulfide to aq. soln. of platinum compd., stirring for 24 h; evapn. at 25°C in vac., extn. (hot benzene), filtration, concg., cooling to 0°C, filtration, washing with hexane, NMR;

DOI:10.1021/om700997v

Reference yield:

{Pt2} (148832-26-2) → cis-dichlorobis(diethylsulfide)platinum(II) (14873-92-8,20244-83-1,15337-84-5,15442-57-6)

Guidance literature:

Multi-step reaction with 3 steps

1: water

2: water

3: hydrogenchloride

In hydrogenchloride; water;

DOI:10.1039/JR9300000349

upstream raw materials:

trans-dichlorobis(diethyl sulfide)platinum(II)

diethyl sulphide

potassium tetrachloroplatinate(II)

hydrogenchloride

Downstream raw materials:

{PtBr2}

trans-dichlorobis(diethyl sulfide)platinum(II)

cis-dichlorobis(diethylsulfide)platinum(II)

{Ptaes₂Cl₄}

Refernces

• 1、 Hansson, Christian. "Cis-Dichloridobis(diethyl sulfide-κS)platinum(II) at 295 and 150 K". . p. m361-m363. Retrieved 2008/09/16.
• 2、 Tobita, Hiromi,Habazaki, Hiroki,Ogino, Hiroshi. "Fast Cis-Trans Isomerization of Square-Planar Bis(diethyl sulfide)platinum(II) Complexes. Reaction of cis-Dichlorobis(diethyl sulfide)platinum(II) with Mesityllithium". . p. 797 - 799. Retrieved 2007/10/02.