2,6-Dimethyl-2,6-octadiene-1,8-diol, (2E,6E)-

Base Information

• Chemical Name: 2,6-Dimethyl-2,6-octadiene-1,8-diol, (2E,6E)-
• CAS No.: 26488-97-1
• Molecular Formula: C10H18 O2
• Molecular Weight: 170.252
• European Community (EC) Number: 684-168-6
• UNII: 6WX29M860A
• Nikkaji Number: J37.635C,J410.202I,J468.947J
• Wikipedia: 8-Hydroxygeraniol
• Wikidata: Q20707312
• Metabolomics Workbench ID: 63261
• Mol file: 26488-97-1.mol

Synonyms:8-hydroxygeraniol

Chemical Property of 2,6-Dimethyl-2,6-octadiene-1,8-diol, (2E,6E)-

Chemical Property:

• Vapor Pressure: 0.000253mmHg at 25°C
• Boiling Point: 288.8°C at 760 mmHg
• Flash Point: 133.5°C
• Density: 0.97g/cm³
• XLogP3: 1.6
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 170.130679813
• Heavy Atom Count: 12
• Complexity: 169

Purity/Quality:

99%, ^*data from raw suppliers

10-Hydroxygeraniol ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=CCO)CCC=C(C)CO
• Isomeric SMILES: C/C(=C\CO)/CC/C=C(\C)/CO
• Uses: 10-Hydroxygeraniol is a volatile compound found in some fruits such as low-flavor kiwifruit species Actinidia eriantha, and Acai (Euterpe oleracea).

Technology Process of 2,6-Dimethyl-2,6-octadiene-1,8-diol, (2E,6E)-

There total 4 articles about 2,6-Dimethyl-2,6-octadiene-1,8-diol, (2E,6E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.8%

Geraniol (106-24-1) → Citronellol (106-22-9) + Nerol (106-25-2) + (E)-2,6-dimethyl-oct-2-ene-1,8-diol (23062-07-9) + (2E,6Z)-2,6-dimethylocta-2,6-diene-1,8-diol (26488-98-2) + 8-hydroxygeraniol (26488-97-1)

Guidance literature:

With 2,4-Dichlorophenoxyacetic acid; sucrose; cultured cells of Catharanthus roseus; In water; at 25 ℃; for 48h; Product distribution; other reaction time;

DOI:10.1016/S0031-9422(96)00566-3

Reference yield:

Nerol (106-25-2) → Citronellol (106-22-9) + Geraniol (106-24-1) + (E)-2,6-dimethyl-oct-2-ene-1,8-diol (23062-07-9) + (2E,6Z)-2,6-dimethylocta-2,6-diene-1,8-diol (26488-98-2) + 8-hydroxygeraniol (26488-97-1)

Guidance literature:

With cultured cells of Catharanthus roseus; Sucrose; In water; at 25 ℃; for 24h; Product distribution; other reaction time;

DOI:10.1016/S0031-9422(96)00566-3

Reference yield:

(R)-Carvone (6485-40-1,2244-16-8) → Citronellol (106-22-9) + Geraniol (106-24-1) + (E)-2,6-dimethyl-oct-2-ene-1,8-diol (23062-07-9) + (2E,6Z)-2,6-dimethylocta-2,6-diene-1,8-diol (26488-98-2) + 8-hydroxygeraniol (26488-97-1)

Guidance literature:

With cultured cells of Catharanthus roseus; Sucrose; In water; at 25 ℃; for 24h; Product distribution; other reaction time;

DOI:10.1016/S0031-9422(96)00566-3

upstream raw materials:

3,7-dimethyl-2E,6-octadien-1-yl acetate

Nerol

Geraniol

(R)-Carvone

Downstream raw materials:

chrysomelidial

2,6-dimethyloctane-1,8-diol

ipolamiide

lamiide

Refernces

• 1、 Madyastha, Madhava K.,Krishna Murthy, N. S. R.. "REGIOSPECIFIC HYDROXYLATION OF ACYCLIC MONOTERPENE ALCOHOLS BY ASPERGILLUS NIGER". . p. 579 - 580. Retrieved 2007/10/02.