Palladium hydroxide

Base Information

• Chemical Name: Palladium hydroxide
• CAS No.: 12135-22-7
• Molecular Formula: H2O2Pd
• Molecular Weight: 140.43
• Hs Code.: 38151200
• European Community (EC) Number: 235-219-2
• UNII: HRE96R2PEX
• DSSTox Substance ID: DTXSID20923782
• Nikkaji Number: J154.801H
• Wikidata: Q4138108
• Mol file: 12135-22-7.mol

Synonyms:Palladium hydroxide;Palladium(II) hydroxide;Palladium hydroxide on carbon;Pearlman's catalyst;Palladium dihydroxide;Palladium hydroxide (Pd(OH)2);H2O2Pd;Pearlmans Catalyst;dihydroxypalladium;palladiumhydroxide;Pearlman catalyst;Peariman's catalyst;Pearl man's catalyst;Palladium(II)hydroxide;Pd(OH)2 on charcoal;Palladium hydroxide 20wt.% Pd on carbon;palladium (ii) hydroxide;palladium hydroxide/carbon;palladium-(II) hydroxide;palladium-(II)-hydroxide;palladium hydroxide charcoal;palladium hydroxide-charcoal;palladiumhydroxide on carbon;Pd(OH)2/C;H2-O2-Pd;paIIadium hydroxide on carbon;palladiumhydroxide on charcoal;palladiurn hydroxide on carbon;palladium hydroxide on charcoal;DTXSID20923782;PEARLMAN'S CATALYST [MI];NXJCBFBQEVOTOW-UHFFFAOYSA-L;PALLADIUM(2+) DIHYDROXIDE;Palladium hydroxide on carbon(20%);AKOS015904338;BP-12766;FT-0689167;P1528;D79705;J-004482;Q4138108

Chemical Property of Palladium hydroxide

Chemical Property:

• Appearance/Colour: black powder
• Vapor Pressure: 24.5mmHg at 25°C
• Boiling Point: 100 °C at 760 mmHg
• PSA: 46.12000
• Density: 3.44[at 20℃]
• LogP: -0.35360
• Storage Temp.: Inert atmosphere,Room Temperature
• Water Solubility.: INSOLUBLE
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 139.90896
• Heavy Atom Count: 3
• Complexity: 0

Purity/Quality:

99.9% ^*data from raw suppliers

Palladium hydroxide on carbon ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,Xi
• Hazard Codes: F,Xi
• Statements: 11-36/37/38
• Safety Statements: 22-24/25-14-36-26-20/21-36/37/39-33-27-16-7/9

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: [OH-].[OH-].[Pd+2]
• Uses: Palladium hydroxide is usually used as a catalyst for arylation reactions. Nonpyrophoric catalyst for hydrogenolysis of benzyl-nitrogen and benzyl-oxygen bonds. Palladium Hydroxide is a catalyst for hydrogenation reactions as well as in the synthesis of glycopeptides used in obtaining antibodies from autoimmune diseases.

Technology Process of Palladium hydroxide

There total 1 articles about Palladium hydroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

pyrographite (7440-44-0) + palladium dichloride → 10 wt% Pd(OH)2 on carbon (12135-22-7)

Guidance literature:

With hydrogenchloride; sodium carbonate; In water; at 50 - 80 ℃; pH=11.5;

DOI:10.1021/op300162d

upstream raw materials:

pyrographite

Refernces