Scandium trichloride

Base Information

• Chemical Name: Scandium trichloride
• CAS No.: 10361-84-9
• Deprecated CAS: 24307-63-9,63310-94-1,63654-08-0,63654-08-0
• Molecular Formula: Cl₃Sc
• Molecular Weight: 151.315
• Hs Code.: 2827398590
• European Community (EC) Number: 233-799-1
• NSC Number: 132051
• DSSTox Substance ID: DTXSID5042372
• Mol file: 10361-84-9.mol

Synonyms:Scandium(III) chloride;Scandium trichloride;10361-84-9;trichloroscandium;Scandium chloride (ScCl3);Scandium(3+) chloride;Scandium(III) chloride, anhydrous;EINECS 233-799-1;NSC 132051;MFCD00011221;UNII-53PH22NTYW;WLN: SC G3;Scandium chloride (Sc4Cl12);DTXSID5042372;NSC132051;SC10828;LS-144615;Scandium(III) chloride, anhydrous, ScCl3;CS-0085769;Scandium(III) chloride, hydrogen-storage grade, 99.9%;Scandium(III) chloride, anhydrous, powder, 99.9% trace metals basis;Scandium(III) chloride, anhydrous, powder, 99.99% trace metals basis;Scandium(III) chloride, anhydrous (99.99%-Sc) (REO) (H2O, OH < 100 ppm);SCANDIUM CHLORIDE;SCANDIUM CHLORIDE(SCCL3);SCANDIUM TRICHLORIDE;SCANDIUM(III) CHLORIDE

Chemical Property of Scandium trichloride

Chemical Property:

• Appearance/Colour: white to slightly beige powder
• Vapor Pressure: 33900mmHg at 25°C
• Melting Point: 960 °C(lit.)
• Boiling Point: 962.79°C (estimate)
• PSA: 0.00000
• Density: 2.39 g/mL at 25 °C(lit.)
• LogP: 2.06850
• Sensitive.: Hygroscopic
• Water Solubility.: Soluble in water. Insoluble in alcohol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 149.862465
• Heavy Atom Count: 4
• Complexity: 8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Scandium(III) chloride, anhydrous 99.90% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 37/39-26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: Cl[Sc](Cl)Cl
• Uses: Scandium chloride (ScCl3): Sc3+ + 3Cl1- → ScCl3. As mentioned, this compound is used in an electrolytic procedure to produce metallic scandium. Scandium(III) chloride is a Prins cyclization catalyst. Used to form an intermetallic nickel-scandium compound film by potentiostatic cathodic reduction from molten salt mixtures. ScCl3 can be used in the preparation of lithium salt of anionic scandium tetraborohydride complex (LiSc(BH4)4) by forming a ball-milled mixture. LiSc(BH4)4 can be used as a potential hydrogen storage material.

Technology Process of Scandium trichloride

There total 17 articles about Scandium trichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

[Sc(chloride)2(water)4]Cl*(water) (114364-35-1) → scandium(III) chloride (10361-84-9)

Guidance literature:

In neat (no solvent, solid phase); byproducts: H2O; Schlenk techniques; heating Sc compd. under vacuum (1E-3 Torr);

DOI:10.1016/j.poly.2010.02.027

Reference yield: 63.4%

hydrogenchloride (7647-01-0,15364-23-5) + scandium(III) oxide → scandium(III) chloride (10361-84-9)

Guidance literature:

With ammonium chloride; In water; at 125 ℃;

DOI:10.1021/om3010433

Reference yield: 23.12%

scandium(III) oxide + erbium(III) oxide + potassium chloride + chlorine (7782-50-5) → erbium(III) chloride (10138-41-7) + scandium(III) chloride (10361-84-9)

Guidance literature:

With pyrographite; In gas; byproducts: CO; by chlorination-chem. vapor transport react.; mixt. of Er2O3 and Sc2O3 with carbon and KCl (1:1:6:1 at. ratio) placed in alumina reactor and chlorinated with dry Cl2 (20 cm**3/min) at 800 K for 2 h; gas replace by Ar:Cl2 at 800-1300 K; detn. of separation factor;

DOI:10.1016/j.jallcom.2005.02.104

upstream raw materials:

chlorine

aluminium trichloride

scandium(III) chloride hydrate

tetrachloromethane

Downstream raw materials:

tris{S-phenyl-N,N'-bis(trimethylsilyl)sulfurdiimino}scandium(III)

Sc(tropolonate)3

Refernces

• 1、 Kanno, H.,Yamaguchi, T.,Ohtaki, H.. "A Raman Investigation of the Hydration Number of Scandium(III) Ions". . p. 1695 - 1697. Retrieved 1989.
• 2、 Hu, Shanshan,Jiang, Li,Mao, Yini,Tang, Jianfeng,Xian, Pengfei,Yang, Jun. "Temperature sensing performance based on up-conversion luminescence in hydrothermally synthesized Yb3+/Er3+co-doped NaScF4phosphors". . p. 7862 - 7871. Retrieved 2020.
• 3、 Cherkasov,Garifzyanov,Leont'Ev,Davletshin,Koshkin. "Extraction of scandium ions by new aminophosphinyl extractants". . p. 2599 - 2605. Retrieved 2009.
• 4、 Rudolph, Wolfram W.. "Raman spectroscopic studies of scandium(III) hydration in aqueous solution - About the first hydration sphere of Sc(III) in solution". . p. 221 - 238. Retrieved 2000.
• 5、 Ilyukhin,Dobrokhotova,Petrosyants. "[Sc(OH)(H2O)5]2Cl8: Synthesis, structure, and solid-phase thermal transformation". . p. 48 - 54. Retrieved 2008.
• 6、 Zissi,Papatheodorou. "Changes of vibrational modes upon melting solid Cs2NaScCl6, Cs3ScCl6, Cs3Sc2Cl9 and ScCl3". . p. 51 - 57. Retrieved 1999.
• 7、 Wang, Zhi-Chang,Wang, Lin-Shan,Gao, Rong-Jie,Su, Yi. "Thermodynamic study of the rare earth vapour complexes: ScAl2Cl9 and YAl2Cl9". . p. 1887 - 1890. Retrieved 1996.