Silane, dichloromethyloctyl-

Base Information

• Chemical Name: Silane, dichloromethyloctyl-
• CAS No.: 14799-93-0
• Molecular Formula: C9H20Cl2Si
• Molecular Weight: 227.249
• Hs Code.: 29310099
• European Community (EC) Number: 238-863-2
• DSSTox Substance ID: DTXSID90933272
• Nikkaji Number: J227.191E
• Wikidata: Q72466833
• Mol file: 14799-93-0.mol

Synonyms:14799-93-0;Dichloromethyloctylsilane;n-Octylmethyldichlorosilane;Silane, dichloromethyloctyl-;dichloro(methyl)(octyl)silane;dichloro-methyl-octylsilane;Methyloctyldichlorosilane;C9H20Cl2Si;Dichloro(methyl)octylsilane;EINECS 238-863-2;Dichloro(methyl)-n-octylsilane;Ctylmethyldichlorosilane;octylmethyldichlorosilane;Methyloctyl dichlorosilane;Silane,dichloromethyloctyl-;Dichloromethyl-N-Ctylsilane;dichloromethyl-n-octylsilane;Dichloro(methyl)octylsilane #;SCHEMBL367667;Dichloro(Methyl)-N-Ctylsilane;QHBMMABVNRSRHW-UHFFFAOYSA-;DTXSID90933272;MFCD00042606;AKOS015848743;FS-4900;CS-0152279;FT-0624720;O0265;D91852

Chemical Property of Silane, dichloromethyloctyl-

Chemical Property:

• Appearance/Colour: colorless clear liquid
• Vapor Pressure: 0.073mmHg at 25°C
• Refractive Index: n20/D 1.444(lit.)
• Boiling Point: 236.4 °C at 760 mmHg
• Flash Point: 98.3 °C
• PSA: 0.00000
• Density: 0.964 g/cm³
• LogP: 4.89650
• Sensitive.: Moisture Sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 7
• Exact Mass: 226.0711326
• Heavy Atom Count: 12
• Complexity: 105

Purity/Quality:

98%,99%, ^*data from raw suppliers

Dichloro(methyl)-n-octylsilane >97.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34-37-29-14
• Safety Statements: 26-36/37/39-45-8

MSDS Files:

Useful:

• Canonical SMILES: CCCCCCCC[Si](C)(Cl)Cl

Technology Process of Silane, dichloromethyloctyl-

There total 10 articles about Silane, dichloromethyloctyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.6%

Dichloromethylsilane (75-54-7) + oct-1-ene (111-66-0,25068-25-1) → dichloro-methyl-octyl-silane (14799-93-0)

Guidance literature:

oct-1-ene; With diethylenetriaminepentaacetic acid (DTPA)-functionalized silica supported Pt; at 60 ℃; for 0.5h;

Dichloromethylsilane; at 60 ℃; for 4h; Reagent/catalyst;

DOI:10.1039/c8ra01828f

Reference yield:

Dichloromethylsilane (75-54-7) + oct-1-ene (111-66-0,25068-25-1) → octane (111-65-9) + dichloro-methyl-octyl-silane (14799-93-0)

Guidance literature:

With iron; at 90 ℃; for 12h; regioselective reaction; Sealed tube;

DOI:10.1080/10426507.2018.1506782

Reference yield:

Dichloromethylsilane (75-54-7) + oct-1-ene (111-66-0,25068-25-1) → me(2-oct)SiCl2 (17869-65-7) + dichloro-methyl-octyl-silane (14799-93-0)

Guidance literature:

upstream raw materials:

Dichloromethylsilane

ethene

oct-1-ene

Methyltrichlorosilane

Downstream raw materials:

methyl(n-octyl)diphenylsilane

1-[(diethoxy)methylsilyl]octane

Refernces

• 1、 Onopchenko, Anatoli,Sabourin, Edward T.. "Tetraalkylsilanes via Hydrosilylation of 1-Alkenes". . p. 64 - 66. Retrieved 1988.
• 2、 Kumada et al.. "". . p. 611. Retrieved 1970.
• 3、 Yang, Xiaoling,Bai, Ying,Li, Jiayun,Dai, Zinan,Peng, Jiajian. "Hydrosilylation of alkenes catalyzed by Fe powder". . p. 1 - 4. Retrieved 2019/02/01.
• 4、 Hu, Wenbin,Xie, Huilin,Yue, Hangbo,Prinsen, Pepijn,Luque, Rafael. "Super-microporous silica-supported platinum catalyst for highly regioselective hydrosilylation". . p. 51 - 55. Retrieved 2017/05/10.