Methylium, chlorobis(dimethylamino)-, chloride

Base Information

• Chemical Name: Methylium, chlorobis(dimethylamino)-, chloride
• CAS No.: 56043-45-9
• Molecular Formula: C₅H₁₂ClN₂*Cl
• Molecular Weight: 171.07
• Mol file: 56043-45-9.mol

Synonyms:

Chemical Property of Methylium, chlorobis(dimethylamino)-, chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Methylium, chlorobis(dimethylamino)-, chloride

There total 8 articles about Methylium, chlorobis(dimethylamino)-, chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

tetramethylurea (632-22-4) → N,N,N',N'-tetramethylchlorformamidinium chloride (56043-45-9,13829-06-6)

Guidance literature:

With oxalyl dichloride; In chloroform; at 105 ℃; for 18h; Inert atmosphere; Schlenk technique;

DOI:10.1002/ejoc.201400120

Reference yield: 96.0%

→ N,N,N',N'-tetramethylchlorformamidinium chloride (56043-45-9,13829-06-6)

Guidance literature:

Reference yield: 95.0%

phosgene (75-44-5) + tetramethylurea (632-22-4) → N,N,N',N'-tetramethylchlorformamidinium chloride (56043-45-9,13829-06-6)

Guidance literature:

In toluene; at 0 - 20 ℃; for 26h;

DOI:10.1002/1099-0682(200108)2001:8<1937::AID-EJIC1937>3.0.CO;2-I

upstream raw materials:

Dimethyltrichloromethylamine

N,N-dimethyl-formamide

tetramethylurea

phosgene

Downstream raw materials:

N''-Phenylacetyl-N,N,N',N'-tetramethylguanidin

Ethoxy-N,N,N',N',N,N-hexamethylmethantriamin

N''-(4-Methylbenzoyl)-N,N,N',N'-tetramethylguanidin

2,6-ditert-butyl-7,7-bis(dimethylamino)quinone methide

Refernces

• 1、 Moscardini, Aldo,Mezzetta, Andrea,Calisi, Nicola,Caporali, Stefano,Pomelli, Christian Silvio,Guazzelli, Lorenzo,Chiappe, Cinzia. "Investigation of a family of structurally-related guanidinium ionic liquids through XPS and thermal analysis". . p. 280 - 289. Retrieved 2019/01/03.
• 2、 Sch?n, Florian,Biebl, Florian,Greb, Lutz,Leingang, Simone,Grimm-Lebsanft, Benjamin,Teubner, Melissa,Buchenau, S?ren,Kaifer, Elisabeth,Rübhausen, Michael A.,Himmel, Hans-J?rg. "On the Metal Cooperativity in a Dinuclear Copper–Guanidine Complex for Aliphatic C?H Bond Cleavage by Dioxygen". . p. 11257 - 11268. Retrieved 2019/07/18.