Bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine oxide

Base Information Edit

Chemical Name:Bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine oxide
CAS No.:535925-40-7
Molecular Formula:C30H47O3P
Molecular Weight:486.675
Hs Code.:2919900090
DSSTox Substance ID:DTXSID20463956
Wikidata:Q82289072
Mol file:535925-40-7.mol

Synonyms:Bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine oxide;535925-40-7;(DTBM)2P(O)H;bis(3,5-ditert-butyl-4-methoxyphenyl)-oxophosphanium;SCHEMBL1304839;DTXSID20463956;CLFWKDYYVAJGEC-UHFFFAOYSA-N;FT-0737144;F77631;bis(3,5-di-t-butyl-4-methoxyphenyl)phosphine oxide;Bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphineoxide

Suppliers and Price of Bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine oxide

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
BIS(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINE OXIDE 95.00%
5MG
$ 495.75

Total 2 raw suppliers

Chemical Property of Bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine oxide Edit

Chemical Property:

PSA：59.00000
LogP:7.40430
XLogP3:9.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:8
Exact Mass:485.31845732
Heavy Atom Count:34
Complexity:582

Purity/Quality:

99% ^*data from raw suppliers

BIS(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINE OXIDE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)C1=CC(=CC(=C1OC)C(C)(C)C)[P+](=O)C2=CC(=C(C(=C2)C(C)(C)C)OC)C(C)(C)C

Technology Process of Bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine oxide

There total 4 articles about Bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 1516-96-7
4-bromo-2,6-di-tert-butylanisole

: 535925-40-7
bis(3,5-di-tert-butyl-4-methoxy-phenyl)phosphine oxide

Guidance literature:: 4-bromo-2,6-di-tert-butylanisole; With iodine; magnesium; In tetrahydrofuran; diethyl ether; at 60 ℃; for 1h; Inert atmosphere;

With phosphonic acid diethyl ester; In tetrahydrofuran; diethyl ether; at 60 ℃; for 12h; Inert atmosphere;
DOI:10.1021/jacs.8b09565

Reference yield: 20.5%

: 96-36-6,868-85-9
methyl phosphite

: 1516-96-7
4-bromo-2,6-di-tert-butylanisole

: 535925-40-7
bis(3,5-di-tert-butyl-4-methoxy-phenyl)phosphine oxide

Guidance literature:: 4-bromo-2,6-di-tert-butylanisole; With iodine; magnesium; In tetrahydrofuran; at 5 - 53 ℃; for 2h;

methyl phosphite; In tetrahydrofuran; at 5 ℃; for 1h;

With hydrogenchloride; water; In tetrahydrofuran; toluene; at 20 ℃; for 0.5h;

Reference yield: 20.5%

Diethyl phosphonate: 762-04-9,123-22-8
Diethyl phosphonate

: 535925-40-7
bis(3,5-di-tert-butyl-4-methoxy-phenyl)phosphine oxide

Guidance literature:: With iodine; magnesium; In tetrahydrofuran; at 20 ℃; for 1h;

4-bromo-2,6-di-tert-butylanisole; In tetrahydrofuran; at 5 - 53 ℃; for 1h;

Diethyl phosphonate; In tetrahydrofuran; at 5 ℃; for 1h;