METHYL 8-METHYLNONANOATE

Base Information

• Chemical Name: METHYL 8-METHYLNONANOATE
• CAS No.: 5129-54-4
• Molecular Formula: C11H22O2
• Molecular Weight: 186.294
• Hs Code.: 2915900090
• Mol file: 5129-54-4.mol

Synonyms:Nonanoic acid,8-methyl-,methyl ester;8-methylnonanoic acid methyl ester;8-Methyl-nonansaeure-methylester;Isocaprinsaeure-methylester;8-Methyl-pelargonsaeure-methylester;Isocapric Acid Methyl Ester;

Chemical Property of METHYL 8-METHYLNONANOATE

Chemical Property:

• Vapor Pressure: 0.158mmHg at 25°C
• Boiling Point: 214.2oC at 760 mmHg
• Flash Point: 82.9oC
• PSA: 26.30000
• Density: 0.87g/cm3
• LogP: 3.15600

Purity/Quality:

98%min ^*data from raw suppliers

IsocapricAcidMethylEster ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Isocapric Acid Methyl Ester is the ethyl ester of Isocapric Acid (I789250) which can be used for terminal chain branching in fatty alcohols and acids. Isocapric Acid can also be used for the synthesis of the novel bacterial fatty acid 16-methyl-8(Z)-heptadecenoic Acid.

Technology Process of METHYL 8-METHYLNONANOATE

There total 7 articles about METHYL 8-METHYLNONANOATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

methanol (67-56-1) + 8-methylnonanoic acid (5963-14-4) → 8-methylnonanoic acid methyl ester (5129-54-4)

Guidance literature:

With hydrogenchloride;

Reference yield: 13.0%

methyl 6-bromohexanoate (14273-90-6) + isobutylmagnesium bromide (926-62-5) → 8-methylnonanoic acid methyl ester (5129-54-4)

Guidance literature:

With copper(I) bromide; In 1-methyl-pyrrolidin-2-one; at -8 ℃; for 1.33333h; Inert atmosphere;

DOI:10.1021/acs.jnatprod.9b01234

Reference yield:

methanol (67-56-1) + capsaicin (404-86-4,912457-62-6) → 8-methylnonanoic acid methyl ester (5129-54-4) + methyl isononanoate (5129-53-3) + methyl (E)-8-methyl-6-nonenoate (112375-54-9)

Guidance literature:

With water; chloric acid;

upstream raw materials:

methanol

8-methylnonanoic acid

2-[(6-bromohexyl)oxy]tetrahydro-2H-pyran

8-methyl-1-nonanol

Downstream raw materials:

capsiate

Refernces

• 1、 Inoue, Yutaka,Masimbula, Rishni,Matsuura, Hideyuki,Nakashima, Tenki,Nambu, Yurika. "Pennelliisides A-C, 2,3,4-Trisubstituted Acyl Glucoses Isolated from Solanum pennellii". . p. 2337 - 2346. Retrieved 2020.
• 2、 Hassarajani, S. A.,Mithran, S.,Mamdapur, V. R.. "Synthesis of 8-methylnonanol, a common intermediate for dihydrocapsaicin and fresh water mussel component". . p. 429 - 431. Retrieved 2007/10/02.