5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II)

Base Information

• Chemical Name: 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II)
• CAS No.: 14172-92-0
• Molecular Formula: C44H28 N4 Ni
• Molecular Weight: 671.423
• Hs Code.: 29310099
• European Community (EC) Number: 625-443-2
• Mol file: 14172-92-0.mol

Synonyms:Nickel,[5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N21,N22,N23,N24]-, (SP-4-1)-;Nickel, [5,10,15,20-tetraphenylporphinato(2-)]- (8CI); Nickel, [a,b,g,d-tetraphenylporphinato(2-)]-(7CI); Porphine, a,b,g,d-tetraphenyl-, Ni deriv. (6CI); 21H,23H-Porphine, 5,10,15,20-tetraphenyl-,nickel complex; 21H,23H-Porphine, nickel deriv.;(5,10,15,20-Tetraphenylporphyrinato)nickel; (Tetraphenylporphyrinato)nickel;(meso-Tetraphenylporphinato)nickel; (meso-Tetraphenylporphinato)nickel(II);(meso-Tetraphenylporphyrinato)nickel; Nickel5,10,15,20-tetraphenyl-21H,23H-porphyrin; Nickel5,10,15,20-tetraphenylporphyrin; Nickel meso-tetraphenylporphyrin; Nickeltetraphenylporphine; Nickel tetraphenylporphyrin; Nickel(II)5,10,15,20-tetraphenylporphine; Nickel(II) meso-tetraphenylporphyrin;Nickel(II) tetraphenylporphyrin; Tetraphenylporphine nickel complex;[5,10,15,20-Tetraphenylporphinato(2-)]nickel;[meso-Tetraphenylporphinato(2-)]nickel

Chemical Property of 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II)

Chemical Property:

• Appearance/Colour: purple crystalline powder
• Melting Point: >300 °C
• PSA: 34.58000
• LogP: 6.43780
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 670.166739
• Heavy Atom Count: 49
• Complexity: 807

Purity/Quality:

98%,99%, ^*data from raw suppliers

Ni(II)meso-Tetraphenylporphine(1-3%chlorin) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): UN NO.
• Hazard Codes: Xn
• Statements: 20/21/22
• Safety Statements: 37/39-26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Biological Agents -> Porphyrins
• Canonical SMILES: C1=CC=C(C=C1)C2=C3C=CC(=C(C4=CC=C([N-]4)C(=C5C=CC(=N5)C(=C6C=CC2=N6)C7=CC=CC=C7)C8=CC=CC=C8)C9=CC=CC=C9)[N-]3.[Ni+2]

Technology Process of 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II)

There total 36 articles about 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) + nickel(II) acetate tetrahydrate (6018-89-9) → 5,10,15,20-tetraphenylporphinatonickel(II) (14172-92-0)

Guidance literature:

In pyridine; other Radiation; porphyrin, metal salt and pyridine were sealed in a glass tube, microwave power of 300 W, heated from room temp. to 180°C, stirred for 15min, cooled to 50°C; vessel was opened, decanted, TLC (silica gel), UV;

DOI:10.1039/b716181f

Reference yield: 98.0%

nickel(II) acetate tetrahydrate (6018-89-9) + 5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → 5,10,15,20-tetraphenylporphinatonickel(II) (14172-92-0)

Guidance literature:

With sodium acetate; potassium carbonate; In N,N-dimethyl-formamide; chlorobenzene; at 150 ℃;

DOI:10.1016/j.poly.2012.05.038

Reference yield: 98.0%

nickel(II) chloride hexahydrate + 5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → 5,10,15,20-tetraphenylporphinatonickel(II) (14172-92-0)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; chlorobenzene; at 150 ℃;

upstream raw materials:

5,10,15,20-tetraphenyl-21H,23H-porphine

nickel(II) acetate tetrahydrate

5,15,10,20-tetraphenylporphyrin

nickel-tetraphenylporphyrin^(1-)

Downstream raw materials:

2,7,12,17-tetrachloro-5,10,15,20-tetraphenylporphyrinatonickel(II)

nickel-tetraphenylporphyrin^(1-)

[Ni(II)tetraphenylporphyrin](diethylamine)2

Ni(C₄₄H₂₈N₄)(C₃H₇NH₂)2

Refernces

• 1、 Akhigbe, Joshua,Samankumara, Lalith P.,Brückner, Christian. "The breaking and mending of porphyrins: Reductive coupling of secochlorin bisaldehydes". . p. 3524 - 3526. Retrieved 2012.
• 2、 Kim, Haesol,Shin, Dongyup,Yang, Woojin,Won, Da Hye,Oh, Hyung-Suk,Chung, Min Wook,Jeong, Donghyuk,Kim, Sun Hee,Chae, Keun Hwa,Ryu, Ji Yeon,Lee, Junseong,Cho, Sung June,Seo, Jiwon,Kim, Hyungjun,Choi, Chang Hyuck. "Identification of Single-Atom Ni Site Active toward Electrochemical CO2Conversion to CO". . p. 925 - 933. Retrieved 2021/02/03.
• 3、 Alghooneh, Leila,Heydari-turkmani, Akram,Yavari, Hadi,Zakavi, Saeed. "Effect of degree of β-chlorination on photocatalytic activity of meso-tetraphenylporphyrin under homogeneous and nanoscale heterogeneous conditions: Chlorination vs. bromination". . p. 84 - 94. Retrieved 2020/05/13.