1,3,5-Tris(4-aMinophenyl)benzene

Base Information

• Chemical Name: 1,3,5-Tris(4-aMinophenyl)benzene
• CAS No.: 29102-61-2
• Molecular Formula: C24H15N3O6
• Molecular Weight: 441.39200
• Mol file: 29102-61-2.mol

Synonyms:4',4',4''-Trinitro-triphenylbenzol;

Chemical Property of 1,3,5-Tris(4-aMinophenyl)benzene

Chemical Property:

• PSA: 137.46000
• LogP: 7.98180

Purity/Quality:

≥99% ^*data from raw suppliers

4,4''-Dinitro-5'-(4-nitrophenyl)-1,1':3',1''-terphenyl 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,3,5-Tris(4-aMinophenyl)benzene

There total 1 articles about 1,3,5-Tris(4-aMinophenyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

(4-nitrophenyl)ethanone (100-19-6) → 1,3,5-tris(4-nitrophenyl)benzene (29102-61-2) + 1,3-bis(4-nitrophenyl)but-2-en-1-one (7509-21-9,73172-39-1)

Guidance literature:

With zirconocene bis(perfluorooctanesulfonate); In toluene; at 110 ℃; for 24h; chemoselective reaction;

DOI:10.1080/00397911.2010.532277

Reference yield: 95.0%

1,3,5-tris(4-nitrophenyl)benzene (29102-61-2) → 1,3,5-tris(4-aminophenyl)benzene (118727-34-7)

Guidance literature:

With palladium on activated charcoal; hydrogen; In tetrahydrofuran; at 20 ℃; for 3h; under 9000.9 Torr;

DOI:10.1021/ma400496q

Reference yield:

1,3,5-tris(4-nitrophenyl)benzene (29102-61-2) → C45H33N9O9

Guidance literature:

Multi-step reaction with 2 steps

1: palladium 10% on activated carbon; hydrazine hydrate / ethanol / Reflux

2: tetrahydrofuran / 6 h / Reflux

With palladium 10% on activated carbon; hydrazine hydrate; In tetrahydrofuran; ethanol;

DOI:10.1002/anie.201502399

upstream raw materials:

(4-nitrophenyl)ethanone

Downstream raw materials:

1,3,5-tris(4-aminophenyl)benzene

Refernces