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Magnesium,bromo(4-methylphenyl)-

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Name

Magnesium,bromo(4-methylphenyl)-

EINECS N/A
CAS No. 4294-57-9 Density 1.002 g/cm3
PSA 0.00000 LogP 2.64080
Solubility N/A Melting Point >300℃ (acetonitrile ethyl ether )
Formula C7H7BrMg Boiling Point 65-67 °C
Molecular Weight 195.342 Flash Point -1 °F
Transport Information UN 2924 3 Appearance Clear yellow solution
Safety 16-26-33-36/37/39-43-45-27 Risk Codes 12-14-19-34-66-67-20/21/22-11
Molecular Structure Molecular Structure of 4294-57-9 (P-TOLYLMAGNESIUM BROMIDE) Hazard Symbols HighlyF+,CorrosiveC,FlammableF
Synonyms

Magnesium,bromo-p-tolyl- (7CI,8CI);p-Tolylmagnesium bromide (6CI);(4-Methylphenyl)magnesium bromide;(p-Methylphenyl)magnesium bromide;4-Tolylmagnesium bromide;Bromo(4-methylphenyl)magnesium;Bromo(4-tolyl)magnesium;Bromo(p-methylphenyl)magnesium;Bromo-p-tolylmagnesium;

Article Data 24

Magnesium,bromo(4-methylphenyl)- Synthetic route

60-29-7

diethyl ether

537-64-4

bis(p-tolyl)mercury

phenylmagnesium bromide

4294-57-9

para-methylphenylmagnesium bromide

106-38-7

para-bromotoluene

4294-57-9

para-methylphenylmagnesium bromide

Conditions
ConditionsYield
With magnesium In diethyl ether
With iodine; magnesium In tetrahydrofuran for 2h; Irradiation;
With magnesium In tetrahydrofuran
106-38-7

para-bromotoluene

7439-95-4

magnesium

4294-57-9

para-methylphenylmagnesium bromide

Conditions
ConditionsYield
With ethylene dibromide In tetrahydrofuran for 3h; Heating / reflux;
In tetrahydrofuran
In tetrahydrofuran Inert atmosphere;
With iodine In tetrahydrofuran at 20℃;
106-38-7

para-bromotoluene

13482-64-9

bis(chloromethyl)phosphinic chloride

4294-57-9

para-methylphenylmagnesium bromide

Conditions
ConditionsYield
With sodium iodide; sodium hydrogensulfite; magnesium In tetrahydrofuran; diethyl ether; water; butanone
179088-99-4

5-(2-chlorophenyl)-2-(4-methoxybenzyl)tetrazole

106-38-7

para-bromotoluene

3264-82-2

nickel(II) acetylacetonate

4294-57-9

para-methylphenylmagnesium bromide

Conditions
ConditionsYield
With hydrogenchloride; diisobutylaluminium hydride; magnesium; triphenylphosphine In tetrahydrofuran; toluene
4294-57-9

para-methylphenylmagnesium bromide

613-33-2

(4,4'-dimethyl-1,1'-biphenyl)

Conditions
ConditionsYield
With iron(III) chloride; 1,2-dichloro-ethane In diethyl ether for 1h; Heating;100%
With cobalt(II) chloride hexahydrate; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride In tetrahydrofuran at 0℃; for 1h; Inert atmosphere;99%
With iron(III) chloride; 1,2-dichloro-ethane In tetrahydrofuran at 0℃; for 0.0833333h; Ionic liquid; Inert atmosphere;99%
7089-34-1

((Z)-3-Dimethylamino-2-phenyl-allylidene)-dimethyl-ammonium; perchlorate

4294-57-9

para-methylphenylmagnesium bromide

79542-20-4

(E)-2-phenyl-3-(p-tolyl)acrylaldehyde

Conditions
ConditionsYield
In tetrahydrofuran 1.) reflux, 3 h, 2.) room temperature, overnight;100%
4294-57-9

para-methylphenylmagnesium bromide

188608-74-4

1-{2-[(SS)-(p-tolylsulfinyl)]}pyrrolyl cinnamate

C27H24(2)HNO2S

Conditions
ConditionsYield
Stage #1: para-methylphenylmagnesium bromide With copper(l) iodide In tetrahydrofuran at -30℃; for 0.5h;
Stage #2: 1-{2-[(SS)-(p-tolylsulfinyl)]}pyrrolyl cinnamate In tetrahydrofuran at -30℃; for 1h;
Stage #3: With water-d2 In tetrahydrofuran at 20℃; for 12h;
100%
80783-98-8

N-methoxy-N-methylcyclohexanecarboxamide

4294-57-9

para-methylphenylmagnesium bromide

2789-44-8

cyclohexyl(p-tolyl)methanone

Conditions
ConditionsYield
In diethyl ether at -78 - 25℃;100%
4294-57-9

para-methylphenylmagnesium bromide

92491-22-0

tert-butyl 2-phenyldiazene-1-carboxylate

N'-phenyl-N'-p-tolyl-hydrazinecarboxylic acid tert-butyl ester

Conditions
ConditionsYield
In tetrahydrofuran at -100℃;100%

Magnesium,bromo(4-methylphenyl)- Specification

The Magnesium,bromo(4-methylphenyl)-, with the CAS registry number 4294-57-9, is also known as 4-Methylphenylmagnesium bromide. It belongs to the product categories of Classes of Metal Compounds; Grignard Reagents; Grignard Reagents & Alkyl Metals; Mg (Magnesium) Compounds; Synthetic Organic Chemistry; Typical Metal Compounds. This chemical's molecular formula is C7H7BrMg and molecular weight is 195.34. What's more, its systematic name is called Bromo(4-methylphenyl)magnesium. It is clear yellow solution and it should be kept in a dry and airtight place.

Physical properties about Magnesium,bromo(4-methylphenyl)- are: (1)#H bond acceptors: 0; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 1; (4)Polar Surface Area: 0 Å2; (5)Flash Point: -1 °F; (6)Density: 1.002 g/cm3; (7)Boiling Point: 65-67 °C.

Uses of Magnesium,bromo(4-methylphenyl)-: it is used to produce other chemicals. For example, it is used to produce 2-p-Tolyl-furan. This reaction needs catalyst <1,2-Bis(diphenylphosphino)ethane>nickel(II) dichloride and solvent Diethyl ether at ambient temperature. The reaction time is 16 hours. The yield is 85 %.

When you are dealing with this chemical, you should be very careful. This chemical has an extremely low flash point, boiling point and gases can catch fire in contact with air. It may catch fire in contact with air, only need brief contact with an ignition source and have a very low flash point or evolve highly flammable gases in contact with water. In addition, it may destroy living tissue on contact and it may form explosive peroxides. This chemical is harmful by inhalation, in contact with skin and if swallowed and its repeated exposure may cause skin dryness or cracking. Therefore, you should wear suitable protective clothing, gloves and eye/face protection. You should keep away from sources of ignition and take precautionary measures against static discharges. In case of contacting with eyes, you should rinse immediately with plenty of water and seek medical advice. And in case of accident or if you feel unwell seek medical advice immediately.

You can still convert the following datas into molecular structure:
(1) SMILES: Br[Mg]c1ccc(C)cc1
(2) InChI: InChI=1/C7H7.BrH.Mg/c1-7-5-3-2-4-6-7;;/h3-6H,1H3;1H;/q;;+1/p-1/rC7H7BrMg/c1-6-2-4-7(9-8)5-3-6/h2-5H,1H3
(3) InChIKey: ZRJNGFJIBZKXTP-FFKUXIRKAW

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