Journal of Organic Chemistry p. 2257 - 2262 (2017)
Update date:2022-08-11
Topics:
Salacz, Laura
Charpentier, Cyrille
Suffert, Jean
Girard, Nicolas
The desymmetrizing hydroformylation of internal alkenes derived from dihydromuconic acid is described. The study of this reaction afforded easy access to polyfunction aldehydes. After the evaluation of the reactivity of the dimethyl ester derivative with various primary amines, this methodology was used to design a rapid synthesis of (±)-vindeburnol from tryptamine in only two steps.
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