Angewandte Chemie International Edition
10.1002/anie.201802310
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hydrazine under mild reaction conditions.
In sharp contrast to
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At present, we consider that the present dinitrogen reduction
1
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proceeds via a similar reaction pathway using [M(N
2
)(PNP)] (M =
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[7a,10]
complexes worked as key reactive intermediates.
We believe
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Received: ((will be filled in by the editorial staff))
Published online on ((will be filled in by the editorial staff))
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Keywords: ammonia · catalytic reaction · dinitrogen · pincer ligand ·
[
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[
19b,c]
vanadium
molecular dinitrogen into silylamine
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14
[24] We also confirmed by using N2 gas instead of N2 gas that
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Supporting Information for details).
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[
[
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2
a fully characterized mononuclear vanadium–dinitrogen complex 7
[
[
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t
R
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[
[
4
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