Tetrahedron p. 6411 - 6418 (1993)
Update date:2022-08-16
Topics:
Abdou
Yakout
In contrast to the behaviour of the entitled disulfide (1) toward Wittig reagents (2a, b), which undergoes direct and simple nucleophilic displacement reactions giving 71, b, 8 and 9 as the final products, an extensive decomposition occurred when the same disulfide was treated with ylides 2c, d, furnishing the adducts 7c, d, 8 and 12 or 14, respectively. The given structures were based upon analytical, chemical and spectroscopic results.
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