Bulletin of the Chemical Society of Japan p. 2594 - 2598 (1989)
Update date:2022-08-16
Topics:
Kozuka, Seizi
Nitta, Takemi
Tamura, Shoji
Tagaki, Waichiro
Kinetic and stereochemical studies have been conducted on the reaction of (arylthio)trimethylgermanes with 1-aryl-1-bromoethanes.The reaction has been found to obey a first-order kinetic equation.The rates of the reaction of the substituted arylethanes were well-correlated with ?+ constants.Optically active 1-bromo-1-phenylethane gave racemic phenyl 1-phenylethyl sulfide by the reaction with trimethyl(phenylthio)germane.An SNL ionization of 1-aryl-1-bromoethanes has been suggested as the reaction mechanism.
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