Inorganic Chemistry
Article
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Moreels, I. J. Am. Chem. Soc. 2013, 135, 12270−12278.
(16) Xu, J.; Tang, Y.-B.; Chen, X.; Luan, C.-Y.; Zhang, W.-F.; Zapien,
J. A.; Zhang, W.-J.; Kwong, H.-L.; Meng, X.-M.; Lee, S.-T.; Lee, C.-S.
Adv. Funct. Mater. 2010, 20, 4190−4195.
CONCLUSIONS
■
We demonstrate, for the first time, that it is possible to
synthesize Cu−Fe−S nanocrystals exhibiting a strong localized
surface plasmon resonance (LSPR) effect, which has never been
observed to date in this family of semiconductor nanoparticles.
The position of the plasmonic absorption peak can be tuned
from the visible to the near-infrared range by adjusting the
nanocrystal composition, with the most energetic absorption
being observed for nearly stoichiometric CuFeS2 nanocrystals.
Extended analysis of the reaction mixture enabled us to identify
the true chemical constitution of the sulfur precursors and, as a
consequence, to elaborate new synthetic procedures ensuring
high reproducibility of the optical properties of the nanocryst-
als.
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L.; Lesnyak, V. Chem. Mater. 2014, 26, 1442−1449.
(19) Niezgoda, J. S.; Harrison, M. A.; McBride, J. R.; Rosenthal, S. J.
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(20) Liu, X.; Wang, X.; Swihart, M. T. Chem. Mater. 2015, 27, 1342−
1348.
(21) Kovalenko, M. V.; Manna, L.; Cabot, A.; Hens, Z.; Talapin, D.
V.; Kagan, C. R.; Klimov, V. I.; Rogach, A. L.; Reiss, P.; Milliron, D. J.;
Guyot-Sionnest, P.; Konstantatos, G.; Parak, W. J.; Hyeon, T.; Korgel,
B. A.; Murray, C. B.; Heiss, W. ACS Nano 2015, 9, 1012−1057.
(22) Liang, D.; Ma, R.; Jiao, S.; Pang, G.; Feng, S. Nanoscale 2012, 4,
6265−6268.
ASSOCIATED CONTENT
* Supporting Information
The Supporting Information is available free of charge on the
■
S
(23) Aldakov, D.; Lefranco
3756−3776.
̧ is, A.; Reiss, P. J. Mater. Chem. C 2013, 1,
(24) Wiltrout, A. M.; Freymeyer, N. J.; Machani, T.; Rossi, D. P.;
Plass, K. E. J. Mater. Chem. 2011, 21, 19286−19292.
(25) Kumar, P.; Gusain, M.; Kumar, P. S.; Uma, S.; Nagarajan, R.
RSC Adv. 2014, 4, 52633−52636.
Additional experimental procedures, energy-dispersive
spectra, MS spectra, and GC chromatograms (PDF)
(26) Wang, Y.-H. A.; Bao, N.; Gupta, A. Solid State Sci. 2010, 12,
387−390.
(27) Kumar, P.; Uma, S.; Nagarajan, R. Chem. Commun. 2013, 49,
7316−7318.
AUTHOR INFORMATION
Corresponding Author
Notes
■
(28) Mourdikoudis, S.; Liz-Marzan
1465−1476.
́
, L. M. Chem. Mater. 2013, 25,
(29) Wang, W.; Jiang, J.; Ding, T.; Wang, C.; Zuo, J.; Yang, Q. ACS
Appl. Mater. Interfaces 2015, 7, 2235−2241.
The authors declare no competing financial interest.
(30) Wadia, C.; Wu, Y.; Gul, S.; Volkman, S. K.; Guo, J.; Alivisatos, A.
P. Chem. Mater. 2009, 21, 2568−2570.
ACKNOWLEDGMENTS
■
G.G., P.B., and A.P. acknowledge financial support from
National Centre of Science in Poland (NCN, Grant 2015/
17/B/ST4/03837).
(31) Schliehe, C.; Juarez, B. H.; Pelletier, M.; Jander, S.; Greshnykh,
D.; Nagel, M.; Meyer, A.; Foerster, S.; Kornowski, A.; Klinke, C.;
Weller, H. Science 2010, 329, 550−553.
(32) Shao, G.; Chen, G.; Yang, W.; Ding, T.; Zuo, J.; Yang, Q.
Langmuir 2014, 30, 2863−2872.
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