Journal of Organic Chemistry p. 3023 - 3026 (1982)
Update date:2022-08-05
Topics: Experimental terms Benzyl cation Relationship α-Cyano function Charge delocalization Inductive destabilization Conjugative stabilization Cyano group
Gassman, Paul G.
Guggenheim, Thomas L.
The solvolytic behavior of a series of substituted acetophenone cyanohydrin methanesulfonates has been studied in 2,2,2-trifluoroethanol.A ρ value of -6.70 was observed when the rate data was evaluated vs.Brown's ?+ values.
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Doi:10.1039/c4ra09379h
(2014)Doi:10.1002/ejoc.201000634
(2010)Doi:10.1016/0040-4020(82)80202-0
(1982)Doi:10.1039/c6nj04013f
(2017)Doi:10.1007/BF00503550
(1982)Doi:10.1016/S0040-4039(00)86953-1
(1982)