N. Arulsamy et al. / Polyhedron 26 (2007) 4737–4745
[17] R.D. Feltham, J. Enemark, Coord. Chem. Rev. 13 (1974) 339.
4745
collected in Table 1. During the final stages of the refine-
ment of 3c an extra intense solvate peak was located in
electron difference maps and was modeled as a water sol-
vate whose presence was confirmed by measurement of
the IR spectrum of other crystals from the same batch
which have a band at 3350 cmꢀ1 attributable to the water
solvate.
[18] H. Okamura, E. Miki, K. Mizumachi, T. Ishimori, Bull. Chem. Soc.
Jpn. 49 (1976) 666.
[19] M.E. Chacon Villalba, A. Navaza, J.A. Guida, E.L. Varetti, P.J.
Aymonino, Inorg. Chim. Acta 359 (2006) 707.
[20] B. Jezowska-Trzebiatowska, J. Hanuza, M. Ostern, J. Ziolkowski,
Inorg. Chim. Acta 6 (1972) 141.
[21] A. Werner, P. Karrer, Helv. Chim. Acta 1 (1918) 54.
[22] P.C. Ford, I.M. Lorkovic, Chem. Rev. 102 (2002) 993.
[23] G.H. Maunder, M.R. Russo, A. Sella, Polyhedron 23 (2004) 2709.
[24] N. Arulsamy, D.S. Bohle, J.A. Imonigie, S. Levine, Angew. Chem. 41
(2002) 2371.
6. Supplementary material
[25] C. Feldmann, M. Jansen, Angew. Chem. 35 (1996) 1728.
[26] C. Feldmann, M.Z. Jansen, Anorg. Allg. Chem. 623 (1997) 1803.
[27] M.N. Hughes, Quart. Rev., Chem. Soc. 22 (1968) 1.
[28] N. Arulsamy, D.S. Bohle, J.A. Imonigie, E.S. Sagan, Inorg. Chem. 38
(1999) 2716.
[29] J.A. Hrabie, L.K. Keefer, Chem. Rev. 102 (2002) 1135.
[30] T.M. Anderson, W.A. Neiwert, M.L. Kirk, P.M.B. Piccoli, A.J.
Schultz, T.F. Koetzle, D.G. Musaev, K. Morokuma, R. Cao, C.L.
Hill, Science 306 (2004) 2074.
CCDC 633311, 633312 and 635099 contain the supple-
mentary crystallographic data for 2 Æ 2CH2Cl2, 3c and 3d.
These data can be obtained free of charge via http://
Cambridge Crystallographic Data Centre, 12 Union Road,
Cambridge CB2 1EZ, UK; fax: (+44) 1223-336-033; or
e-mail: deposit@ccdc.cam.ac.uk.
[31] V.V. Grushin, I.S. Akhrem, M.E. Vol’pin, J. Organomet. Chem. 371
(1989) 403.
[32] E.J. Wharton, J.A. McCleverty, Inorg. Nucl. Chem. Lett. 6 (1970)
549.
Acknowledgements
We gratefully acknowledge NSERC for support in the
form of a Discovery Grant and the Air Force Office of Sci-
entific Research, Grants F49620-96-1-0417 and 98-1-0461,
for their financial support of this research.
[33] C.G. Pierpont, D.G. Van Derveer, W. Durland, R. Eisenberg, J. Am.
Chem. Soc. 92 (1970) 4760.
[34] K.R. Grundy, K.R. Laing, W.R. Roper, J. Chem. Soc., Chem.
Commun. (1970) 1500.
[35] B.C. Paul, S.C. Sarker, R.K. Poddar, J. Coord. Chem. 28 (1993) 245.
[36] E.B. Boyar, A. Dobson, S.D. Robinson, B.L. Haymore, J.C.
Huffman, J. Chem. Soc., Dalton Trans. (1985) 621.
[37] B. Haymore, J.C. Huffman, A. Dobson, S.D. Robinson, Inorg. Chim.
Acta 65 (1982) L231.
References
[1] F. Calderazzo, R. Ercoli, G. Natta, in: I. Wender, P. Pino (Eds.),
Organic Synthesis via Metal Carbonyls, vol. 1, Wiley Interscience,
New York, NY, 1968, pp. 1–272.
[38] J.A. McCleverty, C.W. Ninnes, I. Wolochowicz, J. Chem. Soc.,
Chem. Commun. (1976) 1061.
[39] A. Dobson, S.D. Robinson, J. Organometal. Chem. 99 (1975) C63.
[40] J. Reed, R. Eisenberg, Science 184 (1974) 568.
[41] S. Bhaduri, B.F.G. Johnson, C.J. Savory, J.A. Segal, R.H. Walter, J.
Chem. Soc., Chem. Commun. (1974) 809.
[2] T.W. Hayton, W.S. McNeil, B.O. Patrick, P. Legzdins, J. Am. Chem.
Soc. 125 (2003) 12935.
[3] M. Herberhold, A. Razavi, Angew. Chem., Int. Ed. Engl. 11 (1972)
1092.
[42] S. Bhaduri, B.F.G. Johnson, Trans. Met. Chem. 3 (1978) 156.
[43] G. Piazza, G. Innorta, Inorg. Chim. Acta 70 (1983) 111.
[44] A. Khair, Dhaka University Studies, Part B, Science 31 (1983) 35.
[45] B. Haymore, J.A. Ibers, Inorg. Chem. 14 (1975) 2610.
[46] A.P. Gaughan Jr., B.J. Corden, R. Eisenberg, J.A. Ibers, Inorg.
Chem. 13 (1974) 786.
[4] W.P. Griffith, J. Lewis, G. Wilkinson, J. Chem. Soc. (1958) 3993.
[5] I.H. Suberwal, A.B. Burg, J. Chem. Soc., Chem. Commun. (1970)
1001.
[6] C.P. Brock, J.P. Collman, G. Dolcetti, P.H. Farnham, J.A. Ibers, J.E.
Lester, C.A. Reed, Inorg. Chem. 12 (1973) 1304.
[7] F. Basolo, Chem. Brit. 5 (1969) 505.
[47] S. Bhaduri, G.M. Sheldrick, Acta Crystallogr., Sect. B 31 (1975) 897.
[48] N. Arulsamy, D.S. Bohle, J.A. Imonigie, E.S. Sagan, J. Am. Chem.
Soc. 122 (2000) 5539.
[49] D.S. Bohle, J.A. Imonigie, J. Org. Chem. 65 (2000) 5685.
[50] J. Chatt, R.G. Wilkins, J. Chem. Soc. (1956) 525.
[51] J. Chatt, R.G. Wilkins, J. Chem. Soc. (1952) 273.
[52] A.W. Rudie, D.W. Lichtenberg, M.L. Katcher, A. Davison, Inorg.
Chem. 17 (1978) 2859.
[53] G.M. Whitesides, J.F. Gaasch, E.R. Stedronsky, J. Am. Chem. Soc.
94 (1972) 5258.
[54] J.J. Levison, S.D. Robinson, Chem. Ind. (1969) 1514.
[55] R.G. Goel, Inorg. Nucl. Chem. Lett. 15 (1979) 437.
[56] S.H. Mastin, Inorg. Chem. 13 (1974) 1003.
[8] E.W. Abel, Quart. Rev. 17 (1963) 133.
[9] B.I. Swanson, S.K. Satija, J. Chem. Soc., Chem. Commun. (1973) 40.
[10] S.K. Satija, B.I. Swanson, Inorg. Synth. 16 (1976) 1.
[11] S. Cenini, R. Ugo, G. La Monica, S.D. Robinson, Inorg. Chim. Acta
6 (1972) 182.
[12] S. Bhaduri, B.F.G. Johnson, A. Pickard, P.R. Raithby, G.M.
Sheldrick, C.I. Zuccaro, J. Chem. Soc., Chem. Commun. (1977) 354.
[13] R. Bau, I.H. Sabherwal, A.B. Burg, J. Am. Chem. Soc. 93 (1971)
4926.
[14] H.-C. Boettcher, M. Graf, K. Mereiter, K. Kirchner, Organometallics
23 (2004) 1269.
[15] J.H. MacNeil, P.A. Berseth, E.L. Bruner, T.L. Perkins, Y. Wadia, G.
Westwood, W.C. Trogler, J. Am. Chem. Soc. 119 (1997) 1668.
[16] K. McNeill, R.G. Bergman, J. Am. Chem. Soc. 121 (1999) 8260.
[57] D.A. Phillips, M. Kubota, J. Thomas, Inorg. Chem. 15 (1976) 118.