Tetrahedron Letters p. 7299 - 7300 (1998)
Update date:2022-09-26
Topics:
Surivet, Jean-Philippe
Vatele, Jean-Michel
(+)-Goniodiol 7 and (+)-9-deoxygoniopypyrone 8, belonging to the group of styryllactones, have been synthesized in five steps and 75% yield respectively from C4-esters 1a and 1b. The key step of these syntheses is a triflate-sulfone coupling which allowed a rapid construction of the backbone of the title compounds as well as the efficient installation of a masked Z- acrylate moiety.
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