Journal of Organic Chemistry p. 6591 - 6595 (1991)
Update date:2022-08-05
Topics:
Tabuchi, Toshihiko
Nojima, Masatomo
Ozonolysis of vinyl ethers in the presence of α-diketones provided two types of products, i.e., a Baeyer-Villiger oxidation product and 3-acyl-1,2,4-trioxolane.The evidence suggests that the latter product is labile and, therefore, the former one might be produced by decomposition of the latter.In contrast, 1,2,4-trioxolane-3-carboxylates were stable.As a result, ozonolysis of vinyl ethers in the presence of α-keto esters yielded the expected ozonides in high yield.
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