Journal of Organic Chemistry p. 5390 - 5393 (1986)
Update date:2022-08-03
Topics:
Ngo, M.
Larson, K. R.
Mendenhall, G. D.
The blue, persistent free-radical di-tert-butyliminoxyl, t-Bu2C=NO-radical (1), oxidizes p-hydroquinones and catechol in organic solvents to the corresponding quinones in good yield.With simple phenols, the reaction takes three pathways. 2-Naphthol and 9- phenanthrol are oxidized to the corresponding o-quinones, while 1-naphthol, phenol, and 2,6-di-tert-butylphenol give 4,4-disubstituted oxime ethers.Para-substituted phenols afford cyclohexadienones with one di-tert-butyliminoxyl at the original para position.Some of these adducts can be prepared by cooxidation of 1-H and the phenol with ceric ion.Rate constants for some of the reactions of 1 with phenols have been measured by kinetic EPR spectroscopy.
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