cas 13138-51-7, 1,2,3,3-Tetrachlorobutane | Articles data ｜lookchem

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13138-51-7

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Chlorination of chloroolefins C3-C4
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Levanova,Strizhakova,Sokolov,Aseev,Lapidus
p. 255 - 257
(2007/10/03)

KINETICS AND MECHANISM OF LIQUID-PHASE CHLORINATION OF POLYCHLORINATED BUTENES
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Lavrent'eva, O. V.,Levanova, S. V.,Yakimova, N. A.,Bolonina, E. V.
p. 1563 - 1567
(2007/10/02)

INVESTIGATION IN THE FIELD OF UNSATURATED COMPOUNDS. V. ANOMALOUS CHLORINATION OF ETHYLENE COMPOUNDS CONTAINING A CHLORINE ATOM AT THE DOUBLE BOND
The liquid-phase chlorination of isomeric dichlorobutenes in a nonpolar medium was investigated in the presence of tert-butylpyrocatechol and without additions.The addition of tert-butylpyrocatechol leads to an increase in the yield of the products from anomalous chlorination and to a decrease in the yield of the products from normal addition.Increase in temperature during the chlorination of dichlorobutenes in the absence of tert-butylpyrocatechol promotes the formation of the normal addition products.It was suggested that the anomalous reaction, which leads to chlorides of the allyl and vinyl types, takes place by a molecular mechanism while the normal addition reaction takes place by both mechanism (molecular and radical).
Mkryan, G. G.,Kaplanyan, E. E.,Mkryan, G. M.
p. 1398 - 1402
(2007/10/02)

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Chemical Properties

Melting Point: 28.17°C (estimate)
Boiling Point: 188°Cat760mmHg
Flash Point:66.1°C
Density: 1.394g/cm³
Vapor Pressure: 0.843mmHg at 25°C
Refractive Index: 1.4958
PSA: 0.00000
LogP: 3.02640

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